estimation of uniquac-nrf model parameters for nh3-co2-h2o system

نویسندگان

hassan pahlevanzadeh

amir mohseni ahooei

چکیده

vapor-liquid equilibrium in nh3-co2-h2o system at high pressures has been studied. the uniquac-nrf model for this system was extended by using the goppert 4 maurer reported datas. since the system contains molecules and ionic species the binary interaction parameters considered, where those are of molecule-molecule, molecule-ion and ion-ion types. these interaction parameters are taken as constant values in uniquac-nrf, which are not accurate. in this work the mentioned parameters have been considered as function of temperature in quadratic form. by applying an optimization mathematical program to the uniquac-nrf model and experimental data reported by goppert and maurer the model parameters were obtained in term of temperature. the results of  this model with the new parameters show good agreement with experimental data.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Estimation of UNIQUAC-NRF Model Parameters for NH3-CO2-H2O System

Vapor-liquid equilibrium in NH3-CO2-H2O system at high pressures has been studied. The UNIQUAC-NRF model for this system was extended by using the Goppert 4 maurer reported datas. Since the system contains molecules and ionic species the binary interaction parameters considered, where those are of molecule-molecule, molecule-ion and ion-ion types. These interaction parameters are taken as c...

متن کامل

Physical state model of H2SO4/NH3/H2O-aerosols

A novel model to predict the physical state of atmospheric H2SO4/NH3/H2O aerosol particles C. A. Colberg, B. P. Luo, H. Wernli, T. Koop, and Th. Peter Institute for Atmospheric and Climate Science, Swiss Federal Institute of Technology, Zürich, Switzerland Received: 14 November 2002 – Accepted: 21 November 2002 – Published: 16 December 2002 Correspondence to: C. A. Colberg (christina.colberg@et...

متن کامل

Simulation of NH3/CO2 Two-Stage Low Temperature Refrigeration System

Studied is a kind of NH3/CO2 two-stage low temperature refrigeration system, in which NH3 is used as the refrigerant in the high-temperature stage and CO2 is used as the refrigerant in the low-temperature stage. The performance of the system is simulated and analyzed by changing the mean temperature of the evaporator-condenser and the temperature of the condenser. The mean temperatures of the e...

متن کامل

Performance Analysis of CO2/NH3 Cascade Refrigeration System Using ANNs

In this study, artificial neural networks (ANNs) have been used for performance analysis of a CO2/NH3 cascade refrigeration system using a data set, obtained from a thermodynamic model implemented in EES. Thermodynamic parameters of the system are estimated in terms of condensing temperature of ammonia, evaporating temperature of carbon dioxide, condensing temperature of carbon dioxide and temp...

متن کامل

Investigating the Solubility of CO2 in the Solution of Aqueous K2CO3 Using Wilson-NRF Model

Hot potassium carbonate (PC) solution in comparison with amine solution had a decreased energy of regeneration and a high chemical solubility of . To present vapor and liquid equation (VLE) of this system and predict  solubility, the ion specific non-electrolyte Wilson-NRF local composition model (isNWN) was used in this study; the framework of this model was molecular. Therefore, it was suitab...

متن کامل

A modified extended UNIQUAC model for proteins

A modification of the extended UNIQUAC model is proposed for the description of the non-ideality of protein solutions. Here, the Staverman–Guggenheim combinatorial contribution used in extended UNIQUAC model is replaced by the Flory–Huggins term to take into account the size differences between the protein and solvent. This new model allows an excellent description of the activity coefficients ...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)

ناشر: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

دوره 24

شماره 1 2005

کلمات کلیدی

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023